| Class XII |
Chemistry |
Chemistry-II |
2 |
For naming polyhydric alcohols, the ‘e’ of alkane is retained and the ending ‘ol’ is added. The number of –OH groups is indicated by adding the mul... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
and IUPAC Names of Some Ethers Compound Common name IUPAC name CH 3CH 3 Dimethyl ether Methoxymethane C2H5OC 2 5 Diethyl ether Ethoxyethane CH 3CH ... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
Fig. 7.1: Structures of methanol, phenol and methoxymethane Chemistry 198 Reprint 2026-27 The bond angle in alcohols is slightly less than the tetr... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
oxidised to reported by H.C. Brown in 1959. For alcohol by hydrogen peroxide in the presence of aqueous sodium his studies on boron hydroxide. cont... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
XII) with aldehydes and ketones. The first step of the reaction is the nucleophilic addition of Grignard reagent to the carbonyl group to form an a... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
2 + N 2 HCl +HCl Warm Aniline Benzene diazonium chloride Most of the worldwide 4. From cumene production of phenol is from cumene. Phenol is manufa... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
is lacking in ethers and hydrocarbons. Solubility Solubility of alcohols and phenols in water is due to their ability to form hydrogen bonds with w... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
negative charge is localised on oxygen while in phenoxide ion, the charge is delocalised. The delocalisation of negative charge (structures I-V) ma... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
of a small amount of concentrated sulphuric analgesic, anti- acid. The reaction is reversible, and therefore, water is removed as inflammatory and ... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
stable and therefore are easier toStep 1: Formation of protonated alcohol. form than secondary and primary carbocations; tertiary alcohols are the ... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
heated copper at 573 K, dehydrogenation takes place and an aldehyde or a ketone is formed while tertiary alcohols undergo dehydration. Biological o... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
The yield of the reaction product is poor. facilitate the release of hydrogen ion. Nowadays picric acid is prepared by treating phenol first with c... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
substituted benzal chloride is hydrolysed in the presence of alkali to produce salicylaldehyde. 4. Reaction of phenol with zinc dust Phenol is conv... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
of an enzyme, invertase. Glucose and fructose undergo fermentation in the presence of another enzyme, zymase, which is found in yeast. In wine maki... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
been used widely as an inhalation anaesthetic. But due to its slow effect and an unpleasant recovery The formation of ether is a nucleophilic bimol... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
no ether is formed. For example, the reaction of CH ONa with (CH ) C–Br gives exclusively 2-methylpropene. 3 3 3 It is because alkoxides are not on... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
bonds with water molecule as shown: 7.6.3 Chemical 1. Cleavage of C–O bond in ethers Reactions Ethers are the least reactive of the functional grou... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
in step 2 of the reaction, the departure of leaving group + (HO–CH )3reatesamorestablecarbocation[(CH ) C ],a3 3hereaction follows SN1 mechanism. I... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
yield a mixture of ortho and para nitroanisole. Intext Questions 7.10 Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane start... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
to oxidation. The presence of –OH group in phenols activates the aromatic ring towards electrophilic substitution and directs the incoming group to... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
7.8 While separating a mixture of ortho and para nitrophenols by steam distillation, name the isomer which will be steam volatile. Give reason. 7.9... |
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| Class XII |
Chemistry |
Chemistry-II |
2 |
propene. (vi) Butan-2-one to butan-2-ol. 7.22 Give reason for the higher boiling point of ethanol in comparison to methoxymethane. 223 Alcohols, Ph... |
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| Class XII |
Chemistry |
Chemistry-II |
3 |
Unit Objectives Aldehydes, Ketones After studying this Unit, you will be able to and Carboxylic • write the common and IUPAC names of aldehydes, ke... |
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| Class XII |
Chemistry |
Chemistry-II |
3 |
They are used in many food products and pharmaceuticals to add flavours. Some of these families are manufactured for use as solvents (i.e., acetone... |
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| Class XII |
Chemistry |
Chemistry-II |
3 |
from the carbon of the aldehyde group while in case of ketones the numbering begins from the end nearer to the carbonyl group. The substituents are... |
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