| Class XII |
Chemistry |
Chemistry-II |
4 |
3 b R NH 2 pK b –log K b Larger the value of K ob smaller the value of pK , strbnger is the base. The pK values of few amines are given i... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
C H NH 2 5 2 2 5 2 3 6 5 2 2. Alkylation Amines undergo alkylation on reaction with alkyl halides (refer Unit 6, Class XII). 3. Acylation Aliphatic... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
with nitrous acid at low temperatures (273-278 K) to form diazonium salts, a very important class of compounds used for synthesis of a variety of a... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
of aromatic amines is that of their very high reactivity. Substitution tends to occur at ortho- and para-positions. If we have to prepare monosubst... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
, C2H N6 , 5H , 2 H CH 3H a6d (5 H )2NH 2 2 5 2 (ii) C H NH , (C H ) NH, (C H ) N, C H NH 2 5 2 2 5 2 2 5 3 6 5 2 (iii) CH NH , (CH ) NH, (CH ) N, ... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
a short time in solution at low temperatures (273-278 K). The stability of arenediazonium ion is explained on the basis of resonance. Benzenediazon... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
halogen acid in the presence of copper powder. This is referred as Gatterman reaction. The yield in Sandmeyer reaction is found to be better than G... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
be prepared by direct halogenation. Synthesis The cyano group cannot be introduced by nucleophilic substitution of of Aromatic chlorine in chlorobe... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
electrons on nitrogen. Influence of the number of hydrogen atoms at nitrogen atom on the type of reactions and nature of products is responsible fo... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
undergo Friedel-Crafts reaction. (vi) Diazonium salts of aromatic amines are more stable than those of aliphatic amines. (vii) Gabriel phthalimide ... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
compound indicate the relative configuration of a particular stereoisomer of a compound with respect to configuration of some other compound, confi... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
to toluene (ix) Aniline to benzyl alcohol. 9.9 Give the structures of A, B and C in the following reactions: NaCN OH NaOH Br (i) CH 3H I2 A... |
|
| Class XII |
Chemistry |
Chemistry-II |
4 |
do primary amines have higher boiling point than tertiary amines? (iii) Why are aliphatic amines stronger bases than aromatic amines? Answers to So... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
Unit Biomolecules Objectives After studying this Unit, you will be able to • explain the characteristics of “It is the harmonious and synchronous p... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
not fit in this definition. A large number of their reactions have shown that they contain specific functional groups. Chemically, the carbohydrate... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
and if it contains a keto group, it is known as a ketose. Number of carbon atoms constituting the monosaccharide is also introduced in the name as ... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
chain structure is as shown. It also exists in two cyclic forms which are obtained by the addition of —OH at C5 to the ( ) group. The ring, thus fo... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
of one glucose (I) is linked to C4 of another glucose unit (II). The free aldehyde group can be produced at C1 of second glucose in solution and it... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
the next glucose unit. (iii) Glycogen: The carbohydrates are stored in animal body as glycogen. It is also known as animal starch because its struc... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
The word protein is derived from Greek word, “proteios” which means primary or of prime importance. All proteins are polymers of a-amino acids. 10.... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
S 14. Cysteine HS-CH -2 Cys C 15. Methionine* H3C-S-CH 2CH 2 Met M 16. Phenylalanine* C6H5-CH2- Phe F 17. Tyrosine (p)HO-C6H4-CH2- Tyr Y –CH 2 18. ... |
|
| Class XII |
Computer Science |
Computer Science |
10 |
Ethernet cables, fibre optics, or Wi-Fi. A Local Area Network (LAN) is shown in Figure 10.5. Figure 10.5: A Local Area Network LAN is comparatively... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
10.2.3 Structure You have already read that proteins are the polymers of -amino acids of Proteins and they are connected to each other by peptide b... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
secondary, tertiary and quaternary, each level being more complex than the previous one. (i) Primary structure of proteins: Proteins may have one o... |
|
| Class XII |
Chemistry |
Chemistry-II |
5 |
Fig. 10.2: -Pleated sheet structure o(iv) Quaternary structure of proteins: Some of the proteins proteins are composed of two or more polypeptide c... |
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